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Skibidi, let us dive into the dank world of degenerate orbitals! When electrons hit the subshells, they do not just rush in like goons. No, they spread out, claiming their own space first with parallel spins to minimize that nasty repulsion. Imagine a sigma squad where each orbital holds one electron before they pair up on the fourth, sixth, or eighth round in p, d, and f orbitals. This is the edge of maximum multiplicity, where the unpaired electrons flex their spins and keep energy lowkey. Electron exchange vibes, you know? It is all about those parallel spins and the dance of repulsion!